10 b]Explain the process of biomining via microbial surface adsorption and how it can be used for removing heavy metals like Lead Cadmium Mercury and Arsenic.
Biomining via microbial surface adsorption, also known as bioadsorption or bioremediation, is a biotechnological approach that utilizes microorganisms to remove heavy metals from contaminated environments, such as soil, water, or industrial effluents. This process can be an environmentally friendly and cost-effective method for the removal of heavy metals like lead (Pb), cadmium (Cd), mercury (Hg), and arsenic (As). Here’s how biomining via microbial surface adsorption works:
- Selection of Metal-Resistant Microorganisms: The first step involves the selection or isolation of microorganisms that are known to be metal-resistant or have the ability to tolerate high concentrations of heavy metals. These microorganisms can include bacteria, fungi, or algae. Some of these microorganisms have specialized mechanisms to cope with heavy metal toxicity.
- Biosorption: The selected microorganisms possess binding sites on their cell surfaces, such as cell wall components (e.g., polysaccharides, proteins) or extracellular polymeric substances (EPS), that have a high affinity for heavy metal ions. This binding process is called biosorption. It involves the electrostatic attraction, chelation, or ion exchange between the metal ions and the functional groups on the microbial cell surface.
- Metal Uptake: As the heavy metal ions come into contact with the microorganisms, they bind to the cell surface. The metal ions are essentially “trapped” or immobilized on the microbial cells.
- Bioaccumulation: Over time, as the microorganisms grow and reproduce, the heavy metals continue to be adsorbed onto the microbial cells. This process leads to the accumulation of heavy metals within the biomass of the microorganisms.
- Harvesting and Removal: Once the microbial biomass has accumulated a significant amount of heavy metals, it can be harvested from the contaminated environment. The biomass is then separated from the solution, leaving behind cleaner water or soil.
- Regeneration or Disposal: In some cases, the harvested biomass containing the adsorbed heavy metals can be regenerated or treated to recover the metals for recycling or safe disposal. Alternatively, the biomass may be immobilized or disposed of as hazardous waste, depending on the specific circumstances.